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TerbiumFor fluorescent lamps.
| Atomic Number: | 65 | Atomic Symbol: | Tb |
| Atomic Weight: | 158.9254 | Electron Configuration: | 2-8-26-9-2 |
| Shells: | 2,8,18,27,8,2 | Filling Orbital: | 4f9 |
| Melting Point: | 1360oC | Boiling Point: | 3041oC |
| Description: | Silvery rare earth metal. |
| Uses: | |
History
(Ytterby, a villiage in Sweden)
Discovered by Mosander in 1843.
Terbium is a member of the lanthanide or "rare earth" group of elements.
Occurence
- It is found in cerite, gadolinite, and other minerals along with other rare earths.
- It is recovered commercially from monazite in which it is present to the extent of 0.03%, from xenotime, and from euxenite, a complex oxide containing 1% or more of terbia.
- Terbium has been isolated only in recent years with the development of ion-exchange techniques for separating the rare-earth elements.
- As with other rare earths, it can be produced by reducing the anhydrous chloride or fluoride with calcium metal in a tantalum crucible.
- Calcium and tantalum impurities can be removed by vacuum remelting.
- Other methods of isolation are possible.
Properties
- Terbium is reasonably stable in air.
- It is a silver-gray metal, and is malleable, ductile, and soft enough to be cut with a knife.
- Two crystal modifications exist, with a transformation temperature of 1289C.
- Twenty one isotopes with atomic masses ranging from 145 to 165 are recognized.
- The oxide is a chocolate or dark maroon color.
Uses
- Sodium terbium borate is used in solid-state devices.
- The oxide has potential application as an activator for green phosphors used in color TV tubes.
- It can be used with ZrO2 as a crystal stabilizer of fuel cells which operate at elevated temperature.
- Few other uses have been found.
Costs
The element is priced at about $30/g (99.9%).
Handling
Little is known of the toxicity of terbium.
It should be handled with care as with other lanthanide elements.
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